ExamPlay Dark Logo
Logg på

JEE MAIN - Chemistry (2013 (Offline) - No. 20)

Which one of the following molecules is expected to exhibit diamagnetic behaviour?
N2
O2
S2
C2

Forklaring

Those species which have unpaired electrons are called paramagnetic species.

And those species which have no unpaired electrons are called diamagnetic species.

(A)   $$N_2$$ has 14 electrons.

Moleculer orbital configuration of $$N_2$$

= $${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,{\sigma _{2p_z^2}}$$

Here no unpaired electron present, so it is diamagnetic.

(B)   $$O_2$$ has 16 electrons.

Moleculer orbital configuration of $$O_2$$ is

$${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,\,{\sigma _{2{s^2}}}\,\,\sigma _{2{s^2}}^ * \,\,{\sigma _{2p_z^2}}\,\,{\pi _{2p_x^2}}\,= \,{\pi _{2p_y^2}}\,\pi _{2p_x^1}^ * = \,\,\pi _{2p_y^1}^ * $$

Here 2 unpaired electrons present, so it is paramagnetic.

(C)    $$S_2$$ has 32 electrons.

It also has 2 unpaired electrons like $$O_2$$, so it is paramagnetic.

(D)   $$C_2$$ has 12 electrons.

Moleculer orbital configuration of $$C_2$$

= $${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}$$

Here no unpaired electron present, so it is diamagnetic.

Kommentarer (0)

Logg inn for å kommentere
Annonse
BrainBehindX Inc Logo
©2026; Drevet av BrainBehindX Inc